Enhanced oil droplet aggregation and demulsification by increasing electric field in electrocoagulation

Electrocoagulation (EC) is an efficient technology for removing oil-in-water (O/W) emulsions. However, the role of the electric field in EC for demulsification remains unclear and an obstacle for improving reactor design and operation. Herein, demulsification and oil removal performance by EC under different electric field conditions were investigated. Increasing the EC electric field intensity was beneficial for oil removal, and tandem EC had a higher electric field intensity than parallel EC under the same current density. When the current density was 0.67 mA cm^-2, the chemical oxygen demand (COD) removal rates of tandem EC and parallel EC were 1 136.47 and 745.99 g COD kWh^-1, respectively. Oil droplets were polarized by the electric field, and then aligned and aggregated parallel to the direction of the electric field. Increasing electric field intensity accelerated the aggregation of oil droplets, as verified by physical fluid simulation. Furthermore, results showed a higher Al³⁺ dosage and larger electric field intensity in EC with increasing current density, which was conducive to oil droplet demulsification. These findings provide insight into and a theoretical basis for improving oil removal by EC processes.