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N5 +: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material

Karl O Christe1, William W Wilson1, Jeffrey A Sheehy1

  • 1Propulsion Sciences and Advanced Concepts Division, Air Force Research Laboratory (AFRL/PRS), Edwards Air Force Base, CA 93524 (USA), Fax: (+1) 661-275-5471 (and) Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, CA 90089 (USA).

Angewandte Chemie (International Ed. in English)
|June 29, 2021
PubMed
Summary

The stable pentanitrogen (N5+) cation, a rare polynitrogen species, has been synthesized and characterized. This discovery opens new avenues for nitrogen-based chemistry and materials science.

Keywords:
Density functional calculationsIsotopic labelingNMR spectroscopyNitrogenVibrational spectroscopy

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