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Updated: Oct 31, 2025

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The First Determination of Eu-H Distances by Neutron Diffraction on the Novel Hydrides EuMg2H6 and EuMgH4
Holger Kohlmann1, Franz Gingl1,2, Thomas Hansen3
1Laboratoire de Cristallographie Université de Genève Quai Ernest Ansermet 24, CH-1211 Genève 4 (Switzerland), Fax: (+41) 22-7026108.
Abstract:
Despite the high neutron absorption of natural europium, the crystal structures of two Eu hydrides could be solved from powder diffraction data. EuMg2D6 crystallizes in a novel AB2X6 structure type (see picture), EuMgD4 is isotypic to BaZnF4. The mean Eu-D distances are 258 and 253 pm, respectively.
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