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Updated: Oct 31, 2025

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
Published on: May 15, 2018
Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene
Nikitas G Malliaros1, Ina D Kellner2, Thomas Drewello2
1Department of Chemistry, University of Crete, 70013 Voutes Heraklion, Greece.
Abstract:
A new, one step functionalization of C60 with lactones has been developed. This photochemical approach utilizes a variety of lactonyl radicals deriving from lactones through a hydrogen atom abstraction process mediated by tetrabutylammonium decatungstate [(n-Bu4N)4W10O32]. This reaction provides access to a previously unknown class of materials, namely 1-lactonyl-2-hydro[60]fullerenes. A mechanism for this new reaction has been proposed based mainly on the structure of reaction products and deuterium-incorporated experiments.
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