Silver decorated cobalt carbonate to enable high bifunctional activity for oxygen electrocatalysis and rechargeable...

Rechargeable zinc-air batteries (ZABs) is primarily driven by the couple of oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). Currently,it is still challenging to develop cost-effective, highly efficient, and robust bifunctional catalysts for ZABs. Herein, a novel silver decorated cobalt carbonate (Ag@CoCO₃) hybrid catalyst is proposed as the potential bifunctional catalyst to drive OER and ORR for ZABs. Engineering Ag nanoparticles onto the surface of CoCO₃ microsphere not only facilitates the charge transfer, but also modulates the electronic structure, which are beneficial to intrinsic bifunctional activity. As a result, this Ag@CoCO₃ catalyst yields a substantially enhanced bifunctionality compared to the pristine CoCO₃ catalyst. Moreover, the homemade Ag@CoCO₃ based ZABs provides a high peak power density of 146 mW cm^-2, superior to 107 mW cm^-2 for CoCO₃ based ZABs and 111 mW cm^-2 for commercial Pt/C-IrO₂ based ZABs.