Related Experiment Video
Updated: Oct 31, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
On symmetry breaking of dual polyhedra of non-crystallographic group H3
1Département de Physique, Université de Montréal, Complexe des Sciences, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, H2V 0B3, Québec, Canada.
Abstract:
The study of the polyhedra described in this paper is relevant to the icosahedral symmetry in the assembly of various spherical molecules, biomolecules and viruses. A symmetry-breaking mechanism is applied to the family of polytopes {\cal V}_{H_{3}}(\lambda) constructed for each type of dominant point λ. Here a polytope {\cal V}_{H_{3}}(\lambda) is considered as a dual of a {\cal D}_{H_{3}}(\lambda) polytope obtained from the action of the Coxeter group H3 on a single point \lambda\in{\bb R}^{3}. The H3 symmetry is reduced to the symmetry of its two-dimensional subgroups H2, A1 × A1 and A2 that are used to examine the geometric structure of {\cal V}_{H_{3}}(\lambda) polytopes. The latter is presented as a stack of parallel circular/polygonal orbits known as the `pancake' structure of a polytope. Inserting more orbits into an orbit decomposition results in the extension of the {\cal V}_{H_{3}}(\lambda) structure into various nanotubes. Moreover, since a {\cal V}_{H_{3}}(\lambda) polytope may contain the orbits obtained by the action of H3 on the seed points (a, 0, 0), (0, b, 0) and (0, 0, c) within its structure, the stellations of flat-faced {\cal V}_{H_{3}}(\lambda) polytopes are constructed whenever the radii of such orbits are appropriately scaled. Finally, since the fullerene C20 has the dodecahedral structure of {\cal V}_{H_{3}}(a,0,0), the construction of the smallest fullerenes C24, C26, C28, C30 together with the nanotubes C20+6N, C20+10N is presented.
More Related Videos
12:38Structure of HIV-1 Capsid Assemblies by Cryo-electron Microscopy and Iterative Helical Real-space Reconstruction
Published on: August 9, 2011
10:52Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
Related Concept Videos
Plastic Deformations of Members with a Single Plane of Symmetry
Chirality
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
Gauss's Law: Planar Symmetry
Symmetry
Woodward–Hoffmann Selection Rules and Microscopic Reversibility
Structures of Solids