Boosting the lithium storage performance of tin dioxide by carbon nanotubes supporting and surface engineering

In order to reduce the negative impact of the extra carbon coating on the electrochemical properties of the commonly sandwiched carbon nanotubes@tin dioxide@carbon (CNT@SnO₂@C) composites, the external C coating has been designed as a porous carbon in this work. The well-designed porous carbon coating offers an attractive advantage compared to the common carbon coatings, namely, it can not only better mitigate the volumetric variation of SnO₂ by means of its spongy structure with better flexibility and rich free space, but also accelerate the lithium-ions diffusion by virtue of its open tunnel-like architecture. For this reason, this composite prepared here shows outstanding electrochemical performance stemming from the cooperative effect of inner CNT supporting and externally porous carbon coating, displaying 819.3 and 576.0 mAh g^-1 at 200 and even 1000 mA g^-1 after even 500 cycles, respectively. This surface engineering strategy may be valuable for enhancing the cyclical durability of other metal oxides with higher theoretical specific capacities.