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Assembly of Copolymer and Metal-Organic Framework HKUST-1 to Form Cu2-xS/CNFs Intertwining Network for Efficient
Yuanjuan Bai1,2, Yanran Li2, Gonggang Liu1
1Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China.
Abstract:
The construction of complex intertwined networks that provide fast transport pathways for ions/electrons is very important for electrochemical systems such as water splitting, but a challenge. Herein, a three dimensional (3-D) intertwined network of Cu2-xS/CNFs (x = 0 or 0.04) has been synthesized through the morphology-preserved thermal transformation of the intertwined PEG-b-P4VP/ HKUST-1 hybrid networks. The strong interaction between PEG chains and Cu2+ is the key to the successful assembly of PEG-b-P4VP nanofibers and HKUST-1, which inhibits the HKUST-1 to form individual crystalline particles. The obtained Cu2-xS/CNFs composites possess several merits, such as highly exposed active sites, high-speed electronic transmission pathways, open pore structure, etc. Therefore, the 3-D intertwined hierarchical network of Cu2-xS/CNFs displays an excellent electrocatalytic activity for HER, with a low overpotential (η) of 276 mV to reach current densities of 10 mA cm-2, and a smaller Tafel slope of 59 mV dec-1 in alkaline solution.
