Separation of H₂O/CO₂ Mixtures by MFI Membranes: Experiment and Monte Carlo Study

The separation of CO₂ from gas streams is a central process to close the carbon cycle. Established amine scrubbing methods often require hot water vapour to desorb the previously stored CO₂. In this work, the applicability of MFI membranes for H₂O/CO₂ separation is principally demonstrated by means of realistic adsorption isotherms computed by configurational-biased Monte Carlo (CBMC) simulations, then parameters such as temperatures, pressures and compositions were identified at which inorganic membranes with high selectivity can separate hot water vapour and thus make it available for recycling. Capillary condensation/adsorption by water in the microporous membranes used drastically reduces the transport and thus the CO₂ permeance. Thus, separation factors of α_H2O/CO2 = 6970 could be achieved at 70 °C and 1.8 bar feed pressure. Furthermore, the membranes were tested for stability against typical amines used in gas scrubbing processes. The preferred MFI membrane showed particularly high stability under application conditions.