A Cellulose-Derived Nanofibrous MnO₂-TiO₂-Carbon Composite as Anodic Material for Lithium-Ion Batteries

A bio-inspired nanofibrous MnO₂-TiO₂-carbon composite was prepared by utilizing natural cellulosic substances (e.g., ordinary quantitative ashless filter paper) as both the carbon source and structural matrix. Mesoporous MnO₂ nanosheets were densely immobilized on an ultrathin titania film precoated with cellulose-derived carbon nanofibers, which gave a hierarchical MnO₂-TiO₂-carbon nanoarchitecture and exhibited excellent electrochemical performances when used as an anodic material for lithium-ion batteries. The MnO₂-TiO₂-carbon composite with a MnO₂ content of 47.28 wt % exhibited a specific discharge capacity of 677 mAh g^-1 after 130 repeated charge/discharge cycles at a current rate of 100 mA g^-1. The contribution percentage of MnO₂ in the composite material is equivalent to 95.1% of the theoretical capacity of MnO₂ (1230 mAh g^-1). The ultrathin TiO₂ precoating layer with a thickness ca. 2 nm acts as a crucial interlayer that facilitates the growth of well-organized MnO₂ nanosheets onto the surface of the titania-carbon nanofibers. Due to the interweaved network structures of the carbon nanofibers and the increased content of the immobilized MnO₂, the exfoliation and aggregation, as well as the large volume change of the MnO₂ nanosheets, are significantly inhibited; thus, the MnO₂-TiO₂-carbon electrodes displayed outstanding cycling performance and a reversible rate capability during the Li⁺ insertion/extraction processes.