Synergic Effect of TiO₂ Filler on the Mechanical Properties of Polymer Nanocomposites

Nanocomposites with polymer matrix offer excellent opportunities to explore new functionalities beyond those of conventional materials. TiO₂, as a reinforcement agent in polymeric nanocomposites, is a viable strategy that significantly enhanced their mechanical properties. The size of the filler plays an essential role in determining the mechanical properties of the nanocomposite. A defining feature of polymer nanocomposites is that the small size of the fillers leads to an increase in the interfacial area compared to traditional composites. The interfacial area generates a significant volume fraction of interfacial polymer, with properties different from the bulk polymer even at low loadings of the nanofiller. This review aims to provide specific guidelines on the correlations between the structures of TiO₂ nanocomposites with polymeric matrix and their mechanical properties. The correlations will be established and explained based on interfaces realized between the polymer matrix and inorganic filler. The paper focuses on the influence of the composition parameters (type of polymeric matrix, TiO₂ filler with surface modified/unmodified, additives) and technological parameters (processing methods, temperature, time, pressure) on the mechanical strength of TiO₂ nanocomposites with the polymeric matrix.