Poly(catechol) modified Fe₃O₄ magnetic nanocomposites with continuous high Fenton activity for organic degradation at...

Fe₃O₄ magnetic nanoparticles (MNPs) have been widely used as a recyclable catalyst in Fenton reaction for organic degradation. However, the pristine MNPs suffer from the drawbacks of iron leaching in acidic conditions as well as the decreasing catalytic activity of organic degradation at a pH higher than 3.0. To solve the problems, Fe₃O₄ MNPs were modified by poly(catechol) (Fe₃O₄/PCC MNPs) using a facile chemical co-precipitation method. The poly(catechol) modification improved both the dispersity and the surface negative charges of Fe₃O₄/PCC MNPs, which are beneficial to the catalytic activity of MNPs for organic degradation. Moreover, the poly(catechol) modification enhanced the efficiency of Fe(II) regeneration during Fenton reaction due to the acceleration of Fe(III) reduction by the phenolic/quinonoid redox pair. As a result, the Fenton reaction with Fe₃O₄/PCC MNPs could efficiently degrade organic molecules, exampled by methylene blue (MB), in an expanded pH range between 3.0 and 10.0. In addition, Fe₃O₄/PCC MNPs could be reused up to 8 cycles for the MB degradation with negligible iron leaching of lower than 1.5 mg L^-1. This study demonstrated Fe₃O₄/PCC MNPs are a promising heterogeneous Fenton catalysts for organic degradation.