Simultaneous hydrogen production and ibuprofen degradation by green synthesized Cu₂O/TNTAs photoanode

This study aimed to produce a clean energy, hydrogen, and to remove pollutants simultaneously in water by photoelectrochemical (PEC) method. The photo-anode of cuprous oxide modified titanate nanotube arrays (Cu₂O/TNTAs) was synthesized by using lactic acid, green tea, and coffee as reductants individually. The characterizations of Cu₂O/TNTAs were performed by ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), field emission scanning electron microscope (FE-SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) to investigate the physical and chemical properties such as structure, crystallization, element contents, and optical performance. The electrochemical analyses of Cu₂O/TNTAs showed the photo-current of Cu₂O/TNTAs-t (using green tea as reductant) was 2.4 times higher than pure TNTAs, illustrating the effective separation of electron-hole pairs after Cu₂O modification. The photoelectrochemical performances of Cu₂O/TNTAs-t and Cu₂O/TNTAs-c (using coffee as the reductant) were better than Cu₂O/TNTAs-L (using lactic acid as the reductant) in terms of photo-current density, Ibuprofen degradation, and hydrogen generation, implying that depositing Cu₂O on TNTAs can significantly improve the electron mobility by reducing the recombination rate of electron-hole pairs, which is beneficial to simultaneously ibuprofen degradation and hydrogen production.