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Related Experiment Video

Updated: Oct 29, 2025

A Polyaniline-based Sensor of Nucleic Acids
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A Polyaniline-based Sensor of Nucleic Acids

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Specially Designed Polyaniline/Polypyrrole Ink for a Fully Printed Highly Sensitive pH Microsensor.

Miguel Zea1,2, Robert Texidó3, Rosa Villa1,4

  • 1Instituto de Microelectrónica de Barcelona IMB-CNM (CSIC), Campus Universitat Autònoma de Barcelona, 08193 Cerdanyola del Vallès, Barcelona, Spain.

ACS Applied Materials & Interfaces
|July 6, 2021
PubMed
Summary

A new, fully printed pH sensor uses a special conducting polymer blend for highly sensitive and reproducible healthcare applications. This low-cost, disposable device offers stable pH sensing across a wide range.

Keywords:
inkjet printingpH sensorpolyanilinepolymeric inkpolypyrrole

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Biomedical Engineering

Background:

  • Healthcare applications demand mechanically stable, sensitive, and reproducible pH sensors fabricated using low-cost methods.
  • Existing pH sensing technologies often face limitations in terms of cost, stability, or sensitivity in physiological ranges.

Purpose of the Study:

  • To develop a fully printed pH sensor utilizing a novel conducting polymer formulation for enhanced healthcare applications.
  • To investigate the performance characteristics, including sensitivity, reproducibility, and stability, of the developed printed pH sensor.

Main Methods:

  • Formulation of a conducting polymer blend comprising polyaniline (PANI) and polypyrrole (PPy) with poly(sodium 4-styrenesulfonate) (PSS).
  • Inkjet printing (IJP) of the polymer formulation onto a microelectrode on a flexible substrate, over a gold ink functionalized with phthalocyanine (Pc).
  • Characterization of sensor performance, including sensitivity and reproducibility across a wide pH range (pH 3-10).

Main Results:

  • The printed pH sensor demonstrated good sensitivity in the physiological pH range (7-7.5).
  • The sensor exhibited excellent reproducibility and a linear super-Nernstian response (81.2 ± 0.5 mV/pH unit) from pH 3 to 10.
  • The combination of the PANI/PPy/PSS ink and Pc-functionalized gold ink significantly enhanced sensor sensitivity.

Conclusions:

  • The developed inkjet-printed conducting polymer pH sensor offers a low-cost, disposable, highly sensitive, and stable solution for healthcare applications.
  • This technology opens new opportunities for advanced pH monitoring in the healthcare sector.
  • The sensor's performance, particularly its stability and sensitivity across a broad pH range, makes it suitable for various biomedical uses.