Magnetic sulfur-doped carbons for mercury adsorption

Mercury pollution is a significant threat to the environment and health worldwide. Therefore, effective and low-cost absorbents that are easily scalable are needed for real-world applications. Enlarging the surface area of the materials and doping with heteroatoms are two of the most common strategies to cope with this problem. Sulfur-doped activated carbon synthesized from the carbonization of inverse vulcanized thiopolymers makes it possible to combine both large specific surface area and doping of heteroatoms, resulting in outperformance in mercury uptake against commercial activated carbons. Convenient recovery of mercury absorbents after treatment should be beneficial in mercury collecting and recycling. Therefore, magnetic sulfur-doped carbons (MSCs) were prepared by functionalizing sulfur doped carbons through chemical precipitation with magnetic iron oxides. Besides the characterisations of materials, mercury uptake experiments, such as stactic test, capacity test, impact of solution pH, and mixed ions interferences were performed. These MSCs exhibit high specific surface area (1,329 m²/g), high sulfur content (up to 14.8 wt%), porous structure, low cost, and are convenient for retrieval. MSCs are demonstrated high uptake capacity (187 mg g^-1) and efficiency in mercury solution and multifunctional absorption in mixed ions solution, showing their potential to be applied in water purification and environmental remediation.