Recent advances in the polyurethane-based adsorbents for the decontamination of hazardous wastewater pollutants

The pollution of aquatic systems with noxious organic and inorganic contaminants is a challenging problem faced by most countries. Water bodies are contaminated with diverse inorganic and organic pollutants originating from various diffuse and point sources, including industrial sectors, agricultural practices, and domestic wastes. Such hazardous water pollutants tend to accumulate in the environmental media including living organisms, thereby posing significant environmental health risks. Therefore, the remediation of wastewater pollutants is a priority. Adsorption is considered as the most efficient technique for the removal of pollutants in aqueous systems, and the deployment of suitable adsorbents plays a vital role for the sustainable application of the technique. The present review gives an overview of polyurethane foam (PUF) as an adsorbent, the synthesis approaches of polyurethane, and characterization aspects. Further emphasis is on the preparation of the various forms of polyurethane adsorbents, and their potential application in the removal of various challenging water pollutants. The removal mechanisms, including adsorption kinetics, isotherms, thermodynamics, and electrostatic and hydrophobic interactions between polyurethane adsorbents and pollutants are discussed. In addition, regeneration, recycling and disposal of spent polyurethane adsorbents are reported. Finally, key knowledge gaps on synthesis, characterization, industrial applications, life cycle analysis, and potential health risks of polyurethane adsorbents are discussed.