Efficient Gas and VOC Separation and Pesticide Detection in a Highly Stable Interpenetrated Indium-Organic Framework

The new indium-based organic framework {(Me₂NH₂)[In(BDPO)]·DMF·2H₂O} (1) was successfully constructed by using the oxalamide group modified ligand N,N'-bis(isophthalic acid)oxalamide (H₄BDPO). This framework presents a 2-fold interpenetrating structural characteristic, and the unique polar pore environment leads to a high capture ability for CO₂, C₂H and CH₃OH and good separation ability for CO₂ and C₂H over CH₄ as well as for CH₃OH over C₂H₅OH, which was further verified by an ideal adsorbed solution theory (IAST) calculation. Theoretical simulations pointed out the possible adsorption sites of different adsorbed gases in 1. In addition, the excellent chemical stability and strong luminescence of 1 give it an effective selective detection ability for 2,6-dichloro-4-nitroaniline (DCN) in water with a low detection limit of 3.85 ppm, and the detection mechanism is discussed in detail.