Intra-soil waste recycling provides safety of environment

Amelioration and remediation technology was developed for phosphogypsum utilization in Haplic Chernozem of South-European facies (Rostov Region). The technology comprises phosphogypsum dispersed application into the soil layer of 20-45 cm during intra-soil milling. In the model experiment, the phosphogypsum doses 0 (control), 10, 20, and 40 t ha^-1 were studied. The Cd thermodynamic forms in soil solution were calculated via the developed mathematical chemical-thermodynamic model and program ION-3. The form of ion in soil solution (or water extract) was considered accounting the calcium-carbonate equilibrium (CCE) and association of ion pairs CaCO₃⁰; CaSO₄⁰, MgCO₃⁰, MgSO₄⁰, CaHCO₃⁺, MgHCO₃⁺, NaCO₃^-, NaSO₄^-, CaOH⁺, MgOH⁺. For calculation of the equilibrium of microelements concentration in soil solution ion including heavy metals (HMs), the coefficient of microelement association k_as was proposed. According to calculations, Cd²⁺ ion in soil solution was mostly bounded to associates CdOH⁺, partly to associates CdCO₃⁰ and CdHCO₃⁺. The calculated k_as of Cd was 1.24 units in the control option of experiment and decreased to 0.95 units at phosphogypsum dose 40 t ha^-1. The ratio of "active [Cd²⁺] to total Cd" reduced from 33.5% in control option to 28.0% in the option of phosphogypsum dose 40 t ha^-1. The biogeochemical barrier for penetration of HMs from soil to plant roots was high after application of phosphogypsum. According to calculation by ION-3, the standard soil environmental limitations overestimate the toxicity of Cd in soil solution. New decision for intra-soil milling and simultaneous application of phosphogypsum was developed to provide the environmentally safe waste recycling.