Multivariate analysis of the distribution and formation of trihalomethanes in treated water for human consumption

The disinfection of water for human consumption with chlorine or other compounds produces secondary reactions with the organic matter, generating undesirable disinfection by-products (DBPs). Among these are trihalomethanes (THMs), identified as carcinogenic compounds. This work determined the trihalomethanes concentration, both speciated and total, in treated water distributed and stored in tanks of residential condominiums of different social classes. THMs were quantified using static manual Headspace as preconcentration technique, injecting the vapor phase collected in a GC/FID. The results show that the water distributed to the homes already contains THMs, trichloromethane being the major compound. The Principal Components Analysis (PCA) and Hierarchical Cluster Analysis (HCA) with 60 water samples showed that there is no significant distinction among samples of treated water distributed water and water stored in tanks. This study warns to the importance of controlling the formation of trihalomethanes in water throughout treatment and distribution for users.