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Published on: February 13, 2016
Enhanced membrane fouling control and trace organic compounds removal during microfiltration by coupling coagulation
1School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, PR China.
Abstract:
Coupling electric field, coagulation, and powdered activated carbon (PAC) adsorption in the microfiltration (MF) process was an effective strategy for membrane fouling alleviation and trace organic compounds (TrOCs) elimination. In the electric field, the surface charges of bovine serum albumin (BSA) molecules and kaolin particles distributed along the direction of the electric field and formed electric dipoles, which lowered electrostatic repulsion between BSA-BSA, BSA-kaolin, and kaolin-kaolin, resulting in enhanced particle aggregation and turbidity reduction. Electrophoretic migration also strengthened the interaction between particles and polyaluminum chloride (PACl). Protein removal showed a significant linear correlation with the transmembrane pressure (TMP), and the slope variation of the fitting curves reflected the role of the electric field in the BSA removal and membrane fouling control. Under the synergistic function of electric field, coagulation, and PAC adsorption, the MF system achieved an 80.7% reduction on membrane fouling, an average BSA removal of 76.4%, and TrOCs elimination of 65.3%-81.7%. Electrochemical oxidation was the main contributor to the TrOCs removal when 2.5 V voltage was applied, and could also prolong the service life of PAC.
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