Magnetically Isolable Pt0/Co3O4 Nanocatalysts: Outstanding Catalytic Activity and High Reusability in Hydrolytic Dehydrogenation of Ammonia Borane
Related Experiment Video
Updated: Oct 29, 2025
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Serdar Akbayrak1,2,3, Saim Özkar1
1Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey.
Abstract:
The development of a new platinum nanocatalyst to maximize the catalytic efficiency of the precious noble metal catalyst in releasing hydrogen from ammonia borane (AB) is reported. Platinum(0) nanoparticles are impregnated on a reducible cobalt(II,III) oxide surface, forming magnetically isolable Pt0/Co3O4 nanocatalysts, which have (i) superb catalytic activity providing a record turnover frequency (TOF) of 4366 min-1 for hydrogen evolution from the hydrolysis of AB at room temperature and (ii) excellent reusability, retaining the complete catalytic activity even after the 10th run of hydrolysis reaction. The outstanding activity and stability of the catalyst can be ascribed to the strong interaction between the platinum(0) nanoparticles and reducible cobalt oxide, which is supported by the results of XPS analysis. Pt0/Co3O4 exhibits the highest TOF among the reported platinum-nanocatalysts developed for hydrogen generation from the hydrolysis of AB.
More Related Videos
Related Concept Videos
03:08Hydroboration-Oxidation of Alkenes
02:17Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
02:47Alkynes to Aldehydes and Ketones: Hydroboration-Oxidation
One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.
02:36Regioselectivity and Stereochemistry of Hydroboration
Hydroboration proceeds in a concerted fashion with the attack of borane on the π bond, giving a cyclic four-centered transition state. The –BH2 group is bonded to the less substituted carbon and –H to the more substituted carbon. The concerted nature requires the simultaneous addition of –H and –BH2 across the same face of the alkene giving syn...
02:50Catalysis
02:24Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.