Related Experiment Video
Updated: Oct 29, 2025

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
Why conductivity is not always king - physical properties governing the capacitance of 2D metal-organic
Michał Adam Borysiewicz1, Jin-Hu Dou1, Ivo Stassen1
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA. mdinca@mit.edu.
Abstract:
We report a systematic study on the variation of the physical properties of Ni3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene) in the context of their influence on the capacitive behavior of this material in supercapacitor electrodes prepared using the neat MOF. We find that, for this representative material, the sample morphology has a greater impact on the measured electrode performance than differences in bulk electrical conductivity.
More Related Videos
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
06:53Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Related Concept Videos
MOS Capacitor
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
Capacitor With A Dielectric
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...