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Luminescent silicon nanocrystals appended with photoswitchable azobenzene units
Marco Villa1, Sara Angeloni, Alberto Bianco
1Department of Chemistry Ciamician, University of Bologna, Selmi 2, 40126 Bologna, Italy. paola.ceroni@unibo.it.
Abstract:
Confinement of multiple azobenzene chromophores covalently linked at the surface of luminescent silicon nanocrystals preserves the photoswitching behavior and modulates the nanocrystal polarity. Concomitantly, the thermal Z→E isomerization is strongly accelerated and the nanocrystal luminescence is reduced by an energy transfer process resulting in photosensitized E→Z isomerization.
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