Ultrathin NiSe Nanosheets on Ni Foam for Efficient and Durable Hydrazine-Assisted Electrolytic Hydrogen Production

Hydrazine-assisted electrochemical water splitting is an important avenue toward low cost and sustainable hydrogen production. An efficient and stable bifunctional electrocatalyst for the hydrogen evolution reaction (HER) and the anodic hydrazine oxidation reaction (HzOR) is fundamental to this goal. Herein, we employed a facile method to fabricate ultrathin NiSe nanosheet arrays on nickel foam (NiSe/NF), which exhibits predominant electrocatalytic activity for both HER and HzOR. Our investigations revealed that the excellent electrocatalytic activity of the NiSe/NF mainly arises from the abundant electrocatalytic active sites endowed by the ultrathin nanosheet morphology, the rugged feature of the extended (100) nanosheet surface, the rich presence of Se on the nanosheet surface, and the three-dimensional (3D) porous structure of the NF and other factors such as high conductivity of the NiSe/NF and strong NiSe-NF adhesion. We assembled a hydrazine-boosted electrochemical water splitting cell using NiSe/NF as a bifunctional catalyst for both of the electrodes, and the constructed cell exhibits an ultralow overpotential (310 mV at 10 mA cm^-2), which is robust for 30 h continuous electrolysis in a 1 M KOH electrolyte. This work provides a promising avenue toward low cost, high-efficiency, and stable hydrogen production based on hydrazine-assisted electrolytic water splitting for future.