Fabrication of CoSe@NC nanocubes for high performance potassium ion batteries

Potassium-ion batteries (PIBs) are considered as a promising candidate for large-scale energy storage. While exploring suitable anode materials are of vital need for the practical applications of PIBs. Herein, a well-designed heterostructured anode material CoSe nanocubes wrapped by N-doped carbon (CoSe@NC), has been successfully fabricated by simple annealing ZIF-67 nanocubes followed by in-situ selenization process. It is noted that ZIF-67 nanocubes are used as an effective template for the formation of porous structure, which can facilitate the construction of heterogeneous interface between CoSe and N-doped carbon (NC), effectively stabilizing CoSe with conversion reaction product Co⁰, increasing the diffusion mobility of electrons and K⁺-ions, and alleviating huge volume change. As expected, the heterostructured CoSe@NC nanocubes exhibit excellent K⁺-storage performance, which can display a rather high initial charge capacity (388.7 mAh g^-1 at 0.1 A g^-1 with the columbic efficiency of 70%), superior cyclic stability (309.6 mA h g^-1 after 500 cycles at 2 A g^-1), and exceptional rate capability (365.9 mAh g^-1 at 2 A g^-1). In terms of the low-cost and facile production approach for CoSe@NC, which makes the CoSe@NC a promising anode material for PIBs.