Spatially Controlled Preparation of Layered Metallic-Semiconducting Metal Chalcogenide Heterostructures

Spatially controlled preparation of heterostructures composed of layered materials is important in achieving interesting properties. Although vapor-phased deposition methods can prepare vertical and lateral heterostructures, liquid-phased methods, which can enable scalable production and further solution processes, have shown limited controllability. Herein, we demonstrate by using wet chemical methods that metallic Sn_0.5Mo_0.5S₂ nanosheets can be deposited epitaxially on the edges of semiconducting SnS₂ nanoplates to form SnS₂/Sn_0.5Mo_0.5S₂ lateral heterostructures or coated on both the edges and basal surfaces of SnS₂ to give SnS₂@Sn_0.5Mo_0.5S₂ core@shell heterostructures. They also showed good light-to-heat conversion ability due to the metallic property of Sn_0.5Mo_0.5S₂. In particular, the core@shell heterostructure showed a higher photothermal conversion efficiency than the lateral counterpart, largely due to its randomly oriented and polycrystalline Sn_0.5Mo_0.5S₂ layers with larger interfacing area for multiple internal light scattering.