Transformation of phase and heterojunction type by using HAc-adsorbed Bi(NO₃)₃ as a Bi source

Generally, preparing high-efficiency heterojunction photocatalysts via a facile room-temperature route is attractive from the perspective of energy and labor saving. Herein, by using dried and glacial acetic acid (HAc)-adsorbed bismuth nitrate, instead of Bi(NO₃)₃·5H₂O, as a Bi source, a β-Bi₂O₃/Bi₅O₇I heterojunction with well dispersed flowery hierarchical architecture was synthesized, which endows it with high surface area, open channels and good light harvest. More importantly, the change of the precursor achieved a successful transformation for both of phase and heterojunction type, i.e. from type-Ⅰ BiOI/[Bi₆O₅(OH)₃](NO₃)₅·3H₂O (labeled as BiOI/BBN) to Z-scheme β-Bi₂O₃/Bi₅O₇I heterojunction. Since both β-Bi₂O₃ and Bi₅O₇I are visible light responsive, β-Bi₂O₃/Bi₅O₇I exhibited improved visible-light photocatalytic activity for the degradation of tetracycline (TC) and malachite green (MG) with apparent reactant rate (k_app) values about 10 and 11 times higher than those of BiOI/BBN. Besides, the presence of more oxygen vacancies also contributed to the enhancement in photocatalytic performance.