Related Experiment Video
Updated: Oct 28, 2025

Fine-tuning the Size and Minimizing the Noise of Solid-state Nanopores
Published on: October 31, 2013
Role of current fluctuations in nonreversible samplers
Francesco Coghi1, Raphaël Chetrite2, Hugo Touchette3
1School of Mathematical Sciences, Queen Mary University of London, London E1 4NS, England.
Abstract:
It is known that the distribution of nonreversible Markov processes breaking the detailed balance condition converges faster to the stationary distribution compared to reversible processes having the same stationary distribution. This is used in practice to accelerate Markov chain Monte Carlo algorithms that sample the Gibbs distribution by adding nonreversible transitions or nongradient drift terms. The breaking of detailed balance also accelerates the convergence of empirical estimators to their ergodic expectation in the long-time limit. Here, we give a physical interpretation of this second form of acceleration in terms of currents associated with the fluctuations of empirical estimators using the level 2.5 of large deviations, which characterizes the likelihood of density and current fluctuations in Markov processes. Focusing on diffusion processes, we show that there is accelerated convergence because estimator fluctuations arise in general with current fluctuations, leading to an added large deviation cost compared to the reversible case, which shows no current. We study the current fluctuation most likely to arise in conjunction with a given estimator fluctuation and provide bounds on the acceleration, based on approximations of this current. We illustrate these results for the Ornstein-Uhlenbeck process in two dimensions and the Brownian motion on the circle.
More Related Videos
11:33All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
Published on: January 19, 2018
07:57Quantitative Detection of Trace Explosive Vapors by Programmed Temperature Desorption Gas Chromatography-Electron Capture Detector
Published on: July 25, 2014
Related Concept Videos
Sampling Continuous Time Signal
In the...
Sampling Theorem
Sampling Methods: Overview
In analytical chemistry, the choice of...
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Reversible and Irreversible Processes
Aliasing
If the sampling frequency is below the Nyquist rate, these replicas overlap, preventing the original...