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Stochastic order parameter dynamics for phase coexistence in heat conduction.

Shin-Ichi Sasa1, Naoko Nakagawa2, Masato Itami3

  • 1Department of Physics, Kyoto University, Kyoto 606-8502, Japan.

Physical Review. E
|July 17, 2021
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Summary

We developed a model for phase coexistence in steady heat conduction. This model predicts interface temperatures deviating from equilibrium, showing superheated ordered or supercooled disordered states near the interface.

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Area of Science:

  • Thermodynamics
  • Statistical Mechanics
  • Condensed Matter Physics

Background:

  • Phase coexistence is crucial for understanding material properties.
  • Nonequilibrium steady states present challenges for traditional thermodynamics.
  • Previous work suggested deviations from equilibrium transition temperatures in heat conduction.

Purpose of the Study:

  • To propose a stochastic order parameter model for phase coexistence in steady heat conduction.
  • To derive a variational principle for nonequilibrium steady states.
  • To investigate interface temperature behavior and its relation to thermal conductivity.

Main Methods:

  • Stochastic order parameter modeling.
  • Analysis of stochastic dynamics with a nonequilibrium adiabatic boundary condition.
  • Derivation of a variational principle for thermodynamic properties.

Main Results:

  • A variational principle was derived for nonequilibrium steady states.
  • Interface temperature depends on the relative thermal conductivity of ordered and disordered regions.
  • Superheated ordered and supercooled disordered states were predicted near the interface.

Conclusions:

  • The proposed model successfully describes phase coexistence in steady heat conduction.
  • The findings support extended thermodynamics frameworks for nonequilibrium systems.
  • The study highlights the emergence of metastable states in driven systems.