Photoelectrochemical Reduction of Carbon Dioxide with a Copper Graphitic Carbon Nitride Photocathode

Research on the photoreduction of CO₂ often has been dominated by the use of sacrificial reducing agents. A pathway that avoids this problem would be the development of photocathodes for CO₂ reduction that could then be coupled to a photoanodic oxygen evolution reaction. Here, we present the use of copper-substituted graphitic carbon nitride (Cu-CN) on a fluorinated tin oxide (FTO) electrode for the photoelectrochemical two-electron reduction of CO₂ to CO as a major product (>95 %) and formic acid (<5 %). The results show that at a potential of -2.5 V versus Fc\Fc⁺ the CO₂ reduction activity of Cu-CN on FTO electrode improves by 25 % upon illumination by visible light with a faradaic efficiency of nearly 100 %. Independently, X-ray photoelectron spectroscopy conclusively shows a pronounced increase in the electrical conductivity of the Cu-CN upon white light illumination under vacuum and a contactless measuring configuration. This photo-assisted charge mobility is shown to play a key role in the increased reactivity and faradaic efficiency for the reduction of CO₂ .