3D core-shell Fe₃O₄@SiO₂@MoS₂ composites with enhanced microwave absorption performance

In this work, a 3D ternary core-shell Fe₃O₄@SiO₂@MoS₂ composite is synthesized by a hydrothermal technique and a modified Stöber method, where magnetic Fe₃O₄@SiO₂ microsphere with the core of raspberry-like Fe₃O₄ nanoparticles is completely coated by the flower-like MoS₂. Herein, the electromagnetic parameters of the composites are effectively tuned by the combination of magnetic Fe₃O₄ with dielectric SiO₂ and MoS₂. The obtained ternary composites exhibit remarkable enhancement of microwave absorption. The measurement results indicate that the minimum reflection loss (RL) of Fe₃O₄@SiO₂@MoS₂ composites reaches -62.98 dB at 1.83 mm with the effective absorption bandwidth (RL < -10 dB) of 5.76 GHz (from 11.28 to 17.04 GHz) at 1.92 mm, much higher than those of pure Fe₃O₄ particles and Fe₃O₄@SiO₂ microsphere. It is believed that the improved performances come from the specific structural design and the plentiful interfacial construction. Further, the synergistic effect of the dielectric and magnetic loss as well as the promoted impedance matching also help to enhance the microwave absorption of the composites. The microwave absorption behavior of the composites conforms to the quarter-wavelength cancellation theory. Our study offers an effective and promising strategy in the structural design and interfacial construction of the novel magnetic/dielectric composites with high-efficiency microwave absorption.