Porous carbon nanotube microspheres with tailorable surface wettability areas for oil adsorption

Oil adsorption is significant for water purification and environmental protection. However, the conventional bulk sorbents face the predicament of uncontrollable motion as well as hydrophobic nature the whole body, which largely restricts their uptake capacity underwater. Hence, novel adsorbent material for high-efficient oil uptake both at the surface and under the water is urgently required.

We presented a phase-transition lysozyme coating approach to fabricate porous carbon nanotube microspheres with tailorable surface wettability areas for versatile oil adsorption. Because of the existence of magnetic nanoparticle in one hemisphere, the multi-sites coating was easily achieved by constantly changing orientations of the magnetic field. Owing to the integration of various hydrophilic functional groups in lysozyme as well as remarkable adhesion to virtually arbitrary materials, the intrinsically hydrophobic surface of the microspheres was partially modified hydrophilic on multiple sites.

It was demonstrated that the unique surface wettability feature and the porous structure enabled the microspheres to adsorb multiple contaminants both floating on the water and underwater. Besides, the magnetic-responsive ability allowed for controllable collection of oil contaminants. These features, along with the reusability, make the porous carbon nanotube microspheres excellent adsorbents for water purification.