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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
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Flexo-Ionic Effect of Ionic Liquid Crystal Elastomers.

C P Hemantha Rajapaksha1, M D Tharindupriya Gunathilaka2, Suresh Narute3

  • 1Department of Physics, Kent State University, Kent, OH 44240, USA.

Molecules (Basel, Switzerland)
|July 24, 2021
PubMed
Summary
This summary is machine-generated.

Ionic liquid crystal elastomers (iLCEs) exhibit a significant flexo-ionic effect, generating electric signals from mechanical deformation. Their performance, comparable to ionic polymers, shows potential for advanced sensors and energy harvesting devices.

Keywords:
electromechanical couplingflexo-ionic effectflexoelectricityionic liquid crystal elastomersionic liquidsmicropower generationsensors

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Area of Science:

  • Materials Science
  • Soft Matter Physics
  • Polymer Science

Background:

  • Ionic liquid crystal elastomers (iLCEs) are a novel class of materials combining ionic liquid and liquid crystal elastomer properties.
  • The flexo-ionic effect, a mechanical deformation-induced electric signal, is a key phenomenon in electroactive materials.

Purpose of the Study:

  • To investigate the flexo-ionic effect in iLCEs for the first time.
  • To quantify the flexo-ionic coefficients and their dependence on material alignment.
  • To assess the potential of iLCEs for device applications.

Main Methods:

  • Fabrication of iLCE films with controlled director alignment.
  • Measurement of flexo-ionic coefficients under mechanical deformation.
  • Analysis of response times and bandwidth.

Main Results:

  • Flexo-ionic coefficients were found to be highly dependent on director alignment, exceeding 200 µC/m in optimized configurations.
  • These coefficients are significantly higher than those in insulating liquid crystals and comparable to ionic electroactive polymers (iEAPs).
  • Planar alignment (director parallel to substrate) yielded the shortest response times, indicating high bandwidth.

Conclusions:

  • iLCEs demonstrate a remarkable flexo-ionic effect with potential for high performance.
  • Director alignment is a critical factor in optimizing the flexo-ionic response.
  • iLCEs show promise for applications in flexible sensors and wearable micropower generators.