Plasmonic Bi-enhanced ammoniated α-MnS/Bi₂MoO₆ S-scheme heterostructure for visible-light-driven CO₂ reduction

Low redox ability and severe photocorrosion limit the photocatalytic activity of metal sulfides. Herein, step-scheme (S-scheme) heterojunction composited by diethylenetriamine (DETA) ammoniated MnS (α-MnS) and Bi₂MoO₆ with Bi surface plasmon resonance (SPR) was successfully fabricated (Bi-5 %M/BMO). This special electron transport structure effectively suppresses the photocorrosion of α-MnS and makes photocatalysts with high redox ability. DETA was protonated to form positively charged ammonium ions and they are easy to combine with acid gas CO₂, reducing the activation energy of CO₂, building an efficient catalytic reaction system, and improving CO₂ reduction efficiency. The CO evolution rate of Bi-5 %M/BMO (61.11 μmol g^-1h^-1) is 2.42, 7.89 and 5.01 times greater than that of 5 %M/BMO, pure α-MnS hollow spheres and Bi₂MoO₆, respectively. This indicates that Bi SPR effect can promote the separation of photon-generated electron-hole pairs dramatically. The ammoniated S-scheme heterostructure decorated with the SPR effect may provide a new perspective to design heterojunction.