Laser conversion of biomass into porous carbon composite under ambient condition for pH-Universal electrochemical...

It is highly desirable to develop durable and advanced electrocatalysts for pH-universal hydrogen evolution reaction (HER). While it makes much progress so far, the development of an environmental-friendly and cost-effective method to upgrade earth-abundant biomass into high value-added products still remains a major challenge. Thermal pyrolysis method which requires high pyrolysis temperature and long synthesis period is considered as a general method for preparation of carbon-based electrocatalysts. In view of this, ruthenium, nitrogen co-doped porous carbon (Ru@CN) is synthesized by laser conversion method at room temperature using cheap and renewable biomass honey as green carbon source. By controlling the loading of Ru and laser power, the electrocatalytic activities of as-prepared electrocatalysts can be adjusted effectively. Because of the advantage of rich Ru⁰ and Ru-N sites, the synthesized 0.04-Ru@CN-6 with Ru loading amount of 2.66 wt% exhibits a preferable electrocatalytic activity toward HER under all-pH conditions. Especially in alkaline solution, the optimal 0.04-Ru@CN-6 exhibits a small overpotential (11 mV) at 10 mA cm^-2 current density, which is even much better than commercial 20 wt% Pt/C (37 mV). This strategy reported here may be a feasible and unique approach to synthesis and design of high-performance as well as cost-effective all-pH HER electrocatalyst.