Core-shell shaped Ni₂CoHCF@PPy microspheres from prussian blue analogues for high performance asymmetric...

Recently, prussian blue analogues (PBAs), as the most classical class of metal-organic frameworks, have been widely studied by scientists. Nevertheless, the inferior conductivity of PBAs restricts the application in supercapacitors. In this work, nickel cobalt hexacyanoferrate (Ni₂CoHCF) had been produced via a simple co-precipitation approach and coated with polypyrrole on its surface. The conductivity of PBAs was improved by the polypyrrole coating. The Ni₂CoHCF@PPy-400 microspheres were demonstrated to the outstanding specific capacity of 82 mAh g^-1at 1 A g^-1. After 3000 cycles, the Ni₂CoHCF@PPy-400 microspheres had a long cycle life and 86% specific capacity retention rate at 5 A g^-1. Additionally, it was coupled with activated carbon to build high performance asymmetric supercapacitor (Ni₂CoHCF@PPy-400//AC), which displayed a high energy density of 21.7 Wh kg^-1at the power density of 888 W kg^-1and good cycle stability after 5000 cycles (a capacity retention rate of 85.2%). What is more, the results reveal that the Ni₂CoHCF@PPy-400 microspheresare a prospective candidate for exceptional energy storage devices.