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Correction: Selective recognition of DNA defects by cyclometalated Ir(iii) complexes
David Paul Elisa Dayanidhi1, Rosaria Pinky Malapati2, Vaidyanathan Vaidyanathan Ganesan1
1Advanced Materials Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai 600 020, India and Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India.
Dalton Transactions (Cambridge, England : 2003)
|July 28, 2021
Summary
This correction clarifies details regarding cyclometalated iridium(III) complexes for selective DNA defect recognition. It ensures accurate reporting of findings in the original Dalton Transactions publication.
Area of Science:
- Inorganic Chemistry
- Supramolecular Chemistry
- Chemical Biology
Background:
- Cyclometalated iridium(III) complexes offer unique photophysical properties for potential applications in sensing and imaging.
- Selective recognition of DNA defects is crucial for understanding and diagnosing various genetic diseases.
- Previous research explored the use of iridium(III) complexes for DNA interaction studies.
Purpose of the Study:
- To correct and clarify specific details within the original publication concerning iridium(III) complexes and their interaction with DNA defects.
- To ensure the scientific accuracy and reproducibility of the reported findings.
- To provide updated information for researchers in the field of DNA-metal complex interactions.
Main Methods:
- The correction involves re-evaluating and re-stating experimental parameters and data interpretations.
- Spectroscopic techniques and computational methods were employed in the original study.
- The correction ensures precise reporting of the synthesis and characterization of the iridium(III) complexes.
Main Results:
- Specific adjustments are made to the reported binding affinities and selectivity profiles of the iridium(III) complexes towards DNA defects.
- The correction refines the understanding of the mechanism of DNA defect recognition by these complexes.
- Ensures accurate representation of the photophysical properties and their correlation with DNA binding.
Conclusions:
- The corrected findings reinforce the potential of cyclometalated iridium(III) complexes as selective DNA defect sensors.
- Accurate data is essential for advancing the development of diagnostic tools based on metal complexes.
- This correction contributes to the reliable body of knowledge in inorganic and supramolecular chemistry.

