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An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Unifying fluctuation-dissipation temperatures of slow-evolving nonequilibrium systems from the perspective of
Jianhua Zhang1, Wen Zheng1, Shiyun Zhang1
1Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Microscale Magnetic Resonance, Department of Physics, University of Science and Technology of China, Hefei 230026, P. R. China.
Abstract:
For nonequilibrium systems, how to define temperature is one of the key and difficult issues to solve. Although effective temperatures have been proposed and studied to this end, it still remains elusive what they actually are. Here, we focus on the fluctuation-dissipation temperatures and report that such effective temperatures of slow-evolving systems represent characteristic temperatures of their equilibrium counterparts. By calculating the fluctuation-dissipation relation of inherent structures, we obtain a temperature-like quantity T IS For monocomponent crystal-formers, T IS agrees well with the crystallization temperature T c, while it matches with the onset temperature T on for glass-formers. It also agrees with effective temperatures of typical nonequilibrium systems, such as aging glasses, quasi-static shear flows, and quasi-static self-propelled flows. From the unique perspective of inherent structures, our study reveals the nature of effective temperatures and the underlying connections between nonequilibrium and equilibrium systems and confirms the equivalence between T on and T c.
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