Porous materials for carbon dioxide separations

Global investment in counteracting climate change has galvanized increasing interest in carbon capture and sequestration (CCS) as a versatile emissions mitigation technology. As decarbonization efforts accelerate, CCS can target the emissions of large point-source emitters, such as coal- or natural gas-fired power plants, while also supporting the production of renewable or low-carbon fuels. Furthermore, CCS can enable decarbonization of difficult-to-abate industrial processes and can support net CO₂ removal from the atmosphere through bioenergy coupled with CCS or direct air capture. Here we review the development of porous materials as next-generation sorbents for CO₂ capture applications. We focus on stream- and sector-specific challenges while highlighting case studies within the context of the rapidly shifting energy landscape. We conclude with a discussion of key needs from the materials community to expand deployment of carbon capture technologies.