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Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
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A Barium Titanate-on-Oxide Insulator Optoelectronics Platform.
Yu Cao1,2, Siew Li Tan1, Eric Jun Hao Cheung1
1Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, Singapore, 117583, Singapore.
Advanced Materials (Deerfield Beach, Fla.)
|July 29, 2021
Summary
Researchers identified scandate substrates for high-quality barium titanate thin films, enabling advanced optical modulators and on-chip optoelectronics for faster optical communication.
Area of Science:
- Materials Science
- Optoelectronics
- Photonics
Background:
- Electro-optic modulators are crucial for optical communication networks.
- Lithium niobate is a traditional material, but barium titanate offers superior nonlinear properties.
- Barium titanate thin film growth on magnesium oxide often results in degraded crystal quality.
Purpose of the Study:
- To identify suitable substrates for high-quality barium titanate thin films.
- To achieve vertical optical mode confinement in waveguide devices.
- To enable advanced on-chip optoelectronic applications.
Main Methods:
- Identification of scandate-based substrates.
- Evaluation of lattice mismatch and refractive index properties.
- Assessment of crystal quality and optical mode confinement.
Main Results:
- Scandate substrates exhibit small lattice mismatch with barium titanate.
- These substrates provide low refractive index for vertical mode confinement.
- High crystal quality of barium titanate thin films is achieved concurrently.
Conclusions:
- Scandate substrates offer a promising platform for barium titanate-based optical waveguide devices.
- This advancement facilitates nonlinear on-chip optoelectronics.
- Potential applications include Mach-Zehnder modulators, wavelength division multiplexing, and quantum optics-on-chip.

