Related Experiment Video
Updated: Oct 26, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
Published on: January 17, 2020
Heterogeneous Formation of HONO Catalyzed by CO2
Deming Xia1, Xinran Zhang2,3, Jingwen Chen1
1Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), Dalian Key Laboratory on Chemicals Risk Control and Pollution Prevention Technology, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China.
Abstract:
Gas-phase nitrous acid (HONO) is a major precursor of hydroxyl radicals that dominate atmospheric oxidizing capacity. Nevertheless, pathways of HONO formation remain to be explored. This study unveiled an important CO2-catalysis mechanism of HONO formation, using Born-Oppenheimer molecular dynamics simulations and free-energy samplings. In the mechanism, HCO3- formed from CO2 hydrolysis reacts with NO2 dimers to produce HONO at water surfaces, and simultaneously, itself reconverts back to CO2 via intermediates OC(O)ONO- and HOC(O)ONO. A flow system experiment was performed to confirm the new mechanism, which indicated that HONO concentrations with CO2 injections were increased by 29.4-68.5%. The new mechanism can be extended to other humid surfaces. Therefore, this study unveiled a previously overlooked vital role of CO2 that catalyzes formation of HONO and affects atmospheric oxidizing capacity.
More Related Videos
Related Concept Videos
Catalysis
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Aldehydes and Ketones with HCN: Cyanohydrin Formation Mechanism
Aldehydes and Ketones with Alcohols: Hemiacetal Formation
Formation of Halohydrin from Alkenes

