Hurricane/tropical storm rainwater chemistry in the US (from 2008 to 2019)

Rainwater chemistry of extreme rain events is not well characterized. This is despite an increasing trend in intensity and frequency of extreme events and the potential excess loading of elements to ecosystems that can rival annual loading. Thus, an assessment of the loading imposed by hurricane/tropical storm (H/TS) can be valuable for future resiliency strategies. Here the chemical characteristics of H/TS and normal rain (NR) in the US from 2008 to 2019 were determined from available National Atmospheric Deposition Program (NADP) data by correlating NOAA storm tracks with NADP rain collection locations. It found the average pH of H/TS (5.37) was slightly higher (p < 0.05) than that of NR (5.12). On average, H/TS events deposited 14% of rain volume during hurricane season (May to October) at affected collection sites with a maximum contribution reaching 47%. H/TS events contributed a mean of 12% of Ca²⁺, 22% of Mg²⁺, 18% of K⁺, 25% of Na⁺, 7% of NH₄⁺, 6% of NO₃^-, 25% of Cl^- and 11% of SO₄^2- during hurricane season with max loading of 77%, 62%, 94%, 65%, 39%, 34%, 64% and 60%, respectively, which can lead to ecosystems exceeding ion-specific critical loads. Four potential sources (i.e., marine, soil dust, agriculture and industry/fossil fuel) were indicated by PCA. The positive matrix factorization (PMF) suggested Mg²⁺, Na⁺ and Cl^- were primarily marine-originated in both event types, while 36% more sea-salt Ca²⁺ and 33% more sea-salt SO₄^2- were deposited during H/TS. Agriculture and industry/fossil fuel were the main sources of NH₄⁺ and NO₃^-, respectively, in both rain event types. However the NH₄⁺ contribution from industry/fossil fuel increased by 13% during H/TS indicating a potential vehicle source associated with emergency evacuations. This work provides a comprehensive assessment of the rainwater chemistry of H/TS and insight to expected ecosystem loading for future extreme events.