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Published on: October 20, 2023
Development of proton-exchange membrane fuel cell with ionic liquid technology
Kuan Shiong Khoo1, Wen Yi Chia1, Kexin Wang1
1Department of Chemical and Environmental Engineering, Faculty of Science and Engineering, University of Nottingham Malaysia, Broga Road, 43500 Semenyih, Selangor Darul Ehsan, Malaysia.
Ionic liquids (ILs) enhance high-temperature proton exchange membrane fuel cells (HT-PEMFCs) by improving electrolyte conductivity and stability. This review explores ILs in HT-PEMFCs, focusing on materials, fabrication, and greenness for energy solutions.
Area of Science:
- Electrochemistry
- Materials Science
- Green Chemistry
Background:
- Proton exchange membrane fuel cells (PEMFCs) are efficient electrochemical generators converting chemical to electrical energy.
- Traditional PEMFCs face limitations at higher temperatures due to poor electrolyte membrane conductivity.
- Ionic liquids (ILs) offer a promising, greener alternative for enhancing PEMFC performance, especially at elevated temperatures.
Purpose of the Study:
- To review the latest advancements in using ionic liquids (ILs) as electrolytes in high-temperature PEMFCs (HT-PEMFCs).
- To investigate the combination of ILs with polybenzimidazole (PBI) for improved thermal stability, mechanical properties, and proton conductivity.
- To discuss current challenges and future directions in IL-based electrolytes for PEMFCs, including synthesis, fabrication, and experimental techniques.
Main Methods:
- Comprehensive literature review of recent research on ionic liquids in PEMFCs.
- Analysis of electrolyte membranes incorporating ILs, particularly with polybenzimidazole (PBI).
- Evaluation of system fabrication methods, IL synthesis, and experimental techniques for HT-PEMFCs.
Main Results:
- Ionic liquids significantly improve proton conductivity and thermal stability in PEMFC electrolytes.
- ILs combined with PBI demonstrate enhanced mechanical properties and suitability for high-temperature operation.
- ILs present a viable pathway for developing more efficient and durable fuel cell technologies.
Conclusions:
- Ionic liquids are crucial for advancing high-temperature PEMFC technology.
- Further research into IL synthesis, material selection, and system integration is needed for commercialization.
- ILs contribute to sustainable energy solutions by offering greener alternatives in fuel cell applications.
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