A novel γ-like MnO₂ catalyst for ozone decomposition in high humidity conditions

MnO₂ catalysts have been widely studied for catalytic gaseous ozone decomposition. However, their poor moisture resistance often leads to undesirable catalytic effects in the presence of high humidity. In this study, a novel catalyst with γ-like MnO₂ was synthesized using the selective dissolution method on LaMnO₃ perovskites. The as-prepared catalyst exhibited quite stable ozone conversion of ~90% within 12 h under 75% relative humidity (400-800 ppm of ozone, 30 °C, 150 000 mL·g^-1·h^-1 of WHSV). In contrast, traditional γ-MnO₂ catalyst showed deficient resistance to H₂O and sensitivity to space velocity. Detailed characterizations showed that the larger number of oxygen vacancies induced by structure reconstruction of the γ-like MnO₂ and residual La³⁺ cations facilitated ozone decomposition in humid atmosphere. Finally, the reaction rate of ozone decomposition was proposed by a kinetic study, which further proved that the amount and hydrophilicity of oxygen vacancies are the determinants of the first-order reaction rate constant.