Recent advances in lignin-based porous materials for pollutants removal from wastewater

Water pollution is one of the most serious threats facing mankind today and has obtained widespread attention. Significant advances have been made in the past decades to apply porous materials in wastewater treatment, due to their large specific surface areas (S_BET) for interaction with the aimed ions or molecules. However, the majority of porous materials are prepared from fossil-based resources and still possess some drawbacks, such as high cost and non-degradability, which inevitably cause secondary pollution to the environment from their production to disposal. Lignin is the most abundant and the only scalable renewable aromatic resource on earth. Due to its unique physicochemical properties including high carbon content, plentiful functional groups and environmental friendliness, the lignin-based porous materials (LPMs) have shown promising prospects in efficient removal of soluble pollutants from wastewater. In this review, we firstly described the structural and chemical basis of LPMs, following presented the recent progress in the decontamination of heavy metal ions, organic dyes, antibiotics, anions and radionuclides from aqueous systems. Additionally, the outlook was provided to promote more practical implementation of LPMs in the near future.