Sheet-on-sheet TiO₂/Bi₂MoO₆ heterostructure for enhanced photocatalytic amoxicillin degradation

Developing sheet-on-sheet (2D/2D) heterostructure with built-in electric field (BIEF) is effective in boosting the performance of photocatalysts for emerging contaminants degradation. Herein, the 2D/2D microtopography and (-)TiO₂/(+)Bi₂MoO₆ BIEF were precisely integrated into hierarchical nanosheets, which can provide the basis and driving force for charge transfer both in in-plane and interface of heterojunction. The prepared photocatalyst (TiO₂/Bi₂MoO₆) showed high-efficiency and stable performance for photocatalytic amoxicillin (AMX) degradation, which was 18.2 and 5.7 times higher than TiO₂ and Bi₂MoO₆, respectively. More importantly, TiO₂/Bi₂MoO₆ showed more efficient photocatalytic activity and photogenerated charge separation than TiO₂@Bi₂MoO₆ (different morphology). Besides, four possible pathways of AMX degradation were proposed depending on Gaussian calculations and intermediates analysis by GC-MS and HPLC-TOFMS. This work sheds light on the design and construction of unique 2D/2D heterostructure photocatalysts for AMX degradation.