Morphology Engineering of BiVO₄ with CoO_x Derived from Cobalt-containing Polyoxometalate as Co-catalyst for Oxygen...

Bismuth vanadate (BiVO₄ ) as a metal oxidation semiconductor has stimulated extensive attention in the photocatalytic water splitting field. However, the poor transport ability and easy recombination of charge carriers limit photocatalytic water oxidation activity of pure BiVO₄ . Herein, the photocatalytic activity of BiVO₄ is enhanced via adjusting its morphology and combination co-catalyst. First, the Cu-BiVO₄ was synthesized by copper doping to control the growth of {110} facet of BiVO₄ , which is regarded for the separation of photo-generated charge carriers. Then the CoO_x in-situ generated from K₆ [SiCo^II (H₂ O)W₁₁ O₃₉ ] ⋅ 16H₂ O was photo-deposited on Cu-BiVO₄ surface as co-catalyst to speed up reaction kinetics. Cu-BiVO₄ @CoO_x hybrid catalyst shows highest photocatalytic activity and best stability among all the prepared catalysts. Oxygen evolution is about 34.6 μmol in pH 4 acetic acid buffer under 420 nm LED irradiation, which is nearly 20 times higher than that of pure BiVO₄ . Apparent quantum efficiency (AQE) in 1 h and O₂ yield are 1.83% and 23.1%, respectively. O₂ evolution amount nearly maintains the original value even after 5 cycles.