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Updated: Oct 25, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Wigner Crystallization of Electrons in a One-Dimensional Lattice: A Condensation in the Space of States
Massimo Ostilli1, Carlo Presilla2,3
1Instituto de Física, Universidade Federal da Bahia, Salvador 40170-115, Brazil.
Abstract:
We study the ground state of a system of spinless electrons interacting through a screened Coulomb potential in a lattice ring. By using analytical arguments, we show that, when the effective interaction compares with the kinetic energy, the system forms a Wigner crystal undergoing a first-order quantum phase transition. This transition is a condensation in the space of the states and belongs to the class of quantum phase transitions discussed in [M. Ostilli and C. Presilla, J. Phys. A 54, 055005 (2021).JPAMB51751-811310.1088/1751-8121/aba144]. The transition takes place at a critical value r_{s}_{c} of the usual dimensionless parameter r_{s} (radius of the volume available to each electron divided by effective Bohr radius) for which we are able to provide rigorous lower and upper bounds. For large screening length these bounds can be expressed in a closed analytical form. Demanding Monte Carlo simulations allow to estimate r_{s}_{c}≃2.3±0.2 at lattice filling 3/10 and screening length 10 lattice constants. This value is well within the rigorous bounds 0.7≤r_{s}_{c}≤4.3. Finally, we show that if screening is removed after the thermodynamic limit has been taken, r_{s}_{c} tends to zero. In contrast, in a bare unscreened Coulomb potential, Wigner crystallization always takes place as a smooth crossover, not as a quantum phase transition.
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