Related Experiment Video
Updated: Oct 25, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Statistical Mechanics and Thermodynamics: Boltzmann's versus Planck's State Definitions and Counting †
1Institute of Physics, Mathematics and Informatics, Kazakh National Pedagogical Abai University, Almaty 050010, Kazakhstan.
Abstract:
During the physical foundation of his radiation formula in his December 1900 talk and subsequent 1901 article, Planck refers to Boltzmann's 1877 combinatorial-probabilistic treatment and obtains his quantum distribution function, while Boltzmann did not. For this, Boltzmann's memoirs are usually ascribed to classical statistical mechanics. Agreeing with Bach, it is shown that Boltzmann's 1868 and 1877 calculations can lead to a Planckian distribution function, where those of 1868 are even closer to Planck than that of 1877. Boltzmann's and Planck's calculations are compared based on Bach's three-level scheme 'configuration-occupation-occupancy'. Special attention is paid to the concepts of interchangeability and the indistinguishability of particles and states. In contrast to Bach, the level of exposition is most elementary. I hope to make Boltzmann's work better known in English and to remove misunderstandings in the literature.
More Related Videos
08:13Differential Scanning Calorimetry — A Method for Assessing the Thermal Stability and Conformation of Protein Antigen
Published on: March 4, 2017
10:36Author Spotlight: Optimization of Airflow Velocities in Battery Cooling Systems for Enhanced Thermal Performance and Reduced Energy Consumption
Published on: November 3, 2023
Related Concept Videos
Entropy
Entropy
When an ideal gas expands isothermally, the disorder in the gas increases. From the molecular perspective, the gas molecules have more volume to move around in.
Consider an infinitesimal step in the expansion, which...
Third Law of Thermodynamics
Equation of State
Maxwell's Thermodynamic Relations
All thermodynamic potentials are exact differentials. Therefore, their second-order...
Path Between Thermodynamics States