Reduced graphene oxide/TiO₂(B) immobilized on nylon membrane with enhanced photocatalytic performance

Taking advantage of the unique properties of reduced graphene oxide (rGO) and monoclinic crystalline titanium dioxide (TiO₂(B)) nanomaterials, a novel rGO-TiO₂(B) composite membrane (MrGO-TiO₂(B)) was constructed by UV-light-assisted self-assembly of rGO and TiO₂ on a nylon membrane. The structure of MrGO-TiO₂(B) was characterized by scanning electron microscopy, transmission electron microscopy, UV-visible diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis. Through 2D/2D self-assembly, rGO and TiO₂(B) were more tightly combined, and then MrGO-TiO₂(B) exhibited outstanding photocatalytic activity and an excellent methylene blue (MB) removal rate. MB was completely removed in 60 min at a constant rate of 0.042 min^-1 by the MrGO-TiO₂(B)/H₂O₂/MB system upon solar simulating Xe lamp irradiation. The synergistic effect of rGO and TiO₂(B) facilitated the photocatalytic degradation of MB. TiO₂(B) was excited and generated electrons and holes upon irradiation. Some electrons migrated to the surface of TiO₂(B) to react with H₂O₂ to produce hydroxyl radicals (OH), while the other electrons migrated to the surface of rGO to react with H₂O₂, producing OH. In addition, a number of superoxide radicals (O₂^-) was detected. The holes in the valence band of TiO₂(B) directly oxidized MB. The catalytic activity of MrGO-TiO₂(B) toward MB degradation remained stable after four rounds of reuse. Therefore, the surface modification of a nylon membrane with TiO₂(B) and rGO can serve as a promising route to fabricate photocatalytic membranes for use in the water treatment industry.